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Diastereoselective Aldol Reactions with Butane-2,3-diacetal Protected Glyceraldehyde Derivatives.

✍ Scribed by Kristian Rahbek Knudsen; Antonia F. Stepan; Patrick Michel; Steven V. Ley


Publisher
John Wiley and Sons
Year
2006
Weight
34 KB
Volume
37
Category
Article
ISSN
0931-7597

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Butane Diacetal Protected Butane Tetrol Derivatives. -Novel 2,3-butane diacetal-protected trihydroxybutanal (V) [and ent-(V) on analogous ways] is prepared in multigram scale starting from the corresponding protected dimethyl tartrate (I). The approach involves reduction of the diester to the corre