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Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation

✍ Scribed by Dr. Davide Audisio; Dr. Marco Luparia; Maria Teresa Oliveira; Dina Klütt; Dr. Nuno Maulide


Book ID
112001236
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
568 KB
Volume
51
Category
Article
ISSN
0044-8249

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Catalytic Double Stereoinduction in Asym
✍ Barry M. Trost; Yong Zhang 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 311 KB 👁 2 views

## Abstract A highly regio‐, diastereo‐, and enantioselective allylic alkylation reaction of 3‐monosubstituted oxindoles catalyzed by molybdenum is described. The reaction is affected by the electronic and steric variations of the nucleophile. The use of appropriate N‐protecting group is particular