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ChemInform Abstract: Catalytic Double Stereoinduction in Asymmetric Allylic Alkylation of Oxindoles.

✍ Scribed by Barry M. Trost; Yong Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
187 KB
Volume
41
Category
Article
ISSN
0931-7597

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Catalytic Double Stereoinduction in Asym
Catalytic Double Stereoinduction in Asymmetric Allylic Alkylation of Oxindoles
✍ Barry M. Trost; Yong Zhang 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 311 KB 👁 2 views

## Abstract A highly regio‐, diastereo‐, and enantioselective allylic alkylation reaction of 3‐monosubstituted oxindoles catalyzed by molybdenum is described. The reaction is affected by the electronic and steric variations of the nucleophile. The use of appropriate N‐protecting group is particular