Diaquabis(isothiocyanato)bis(4-methylpyridine N-oxide)nickel(II) monohydrate
✍ Scribed by Shi, Jing Min ;Liu, Zhe ;Lu, Jian Jun ;Liu, Lian Dong
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 131 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Ni(NCS) 2 (C 6 H 7 NO) 2 (H 2 O) 2 ]ÁH 2 O, consists of a mononuclear complex and an uncoordinated water molecule. The nickel(II) ion has a distorted octahedral coordination, formed by two N atoms from two thiocyanate anions and four O atoms from two water molecules and two 4methylpyridine N-oxide molecules. The uncoordinated water molecules and the complex are connected by O-HÁ Á ÁO and O-HÁ Á ÁS hydrogen bonds.
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The synthesis, characterization and crystal structure of trans-bis-(4-methylpyridine)bis(8-quinolinolato-N 1,OS)nickel(II)monohydrate