In the title compound, [Cd(C~6~H~7~N~2~O~5~)~2~], the Cd atom lies on an inversion center and has a slightly distorted octahedral geometry. The equatorial plane contains two bidentate 5-carboxy-2-methyl-1__H__-imidazole-4-carboxylate monoanionic ligands. Two coordinated water molecules occupy the ax
✦ LIBER ✦
Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N,O)zinc(II)–4,4′-bipyridine (1/1)
✍ Scribed by Zhong, Rui-Qin ;Zou, Ru-Qiang ;Xu, Qiang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 227 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 295 K Mean (C-C) = 0.003 A R factor = 0.030 wR factor = 0.067 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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In the title neutral mononuclear complex, [Cd(H 2 ID-C) 2 (H 2 O) 3 ]ÁH 2 O (H 2 IDC is the 4-carboxy-1H-imidazole-5carboxylate anion, C 5 H 3 N 2 O 4 ), the Cd II atom is transcoordinated by two H 2 IDC ligands and three aqua molecules, displaying a distorted trigonal-bipyrimidal geometry. Interest