Diaquabis(3,5-dinitrobenzoato)bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-4,5-dihydro-1H-imidazole-1-oxyl-3-oxide]cobalt(II)
✍ Scribed by Zhang, Chen-Xi ;Zhang, Yu-Ying
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 72 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The molecular structure of the title radical compound, C 12 H 16 N 3 O 2 , has crystallographic C 2 symmetry. The dihedral angle between the pyridine and imidazole rings is 25.66 (15) .
The title compound, C~13~H~16~N~4~O~5~·H~2~O, was isolated following the cycloaddition reaction of 4-azidopyridine 1-oxide with an excess of methyl acrylate. The compound arises from a reaction sequence whereby the expected triazoline product undergoes rearrangement and a second cycloaddition reacti
In the title complex, [Hg(NO 3 ) 2 (C 10 H 15 N 3 OS) 2 ], the Hg II ion (site symmetry 1) adopts a grossly distorted octahedral geometry by chelation of two neutral Him-thz ligands [Himthz is 2-(2 0 -thiazole)-4,4,5,5-tetramethyldihydro-1H-imidazolyl-1-hydroxy] through their thiazole N atoms [Hg-N