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Bis[1-hydr­oxy-4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-4,5-dihydro-1H-imidazole]nitratocobalt(II) nitrate

✍ Scribed by Wang, Li-Ya ;Chang, Jiu-Li ;Jiang, Kai ;Ma, Lu-Fang ;Wang, Yu-Fang


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
209 KB
Volume
61
Category
Article
ISSN
1600-5368

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Bis[1-hydroxy-4,4,5,5-tetra­methyl-2-(1,
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In the title complex, [Hg(NO 3 ) 2 (C 10 H 15 N 3 OS) 2 ], the Hg II ion (site symmetry 1) adopts a grossly distorted octahedral geometry by chelation of two neutral Him-thz ligands [Himthz is 2-(2 0 -thiazole)-4,4,5,5-tetramethyldihydro-1H-imidazolyl-1-hydroxy] through their thiazole N atoms [Hg-N

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In the crystal structure of the title compound, C 10 H 17 N 3 O 2 S, the packing of the molecules is mainly a result of two types of O-HÁ Á ÁN hydrogen-bonding interactions, forming a twodimensional network.

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✍ Koketsu, Mamoru ;Ebihara, Masahiro ;Ishihara, Hideharu 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

In the title compound, C~17~H~17~NOS, the phenyl ring at position 6 of the thiazine ring is __trans__ to the hydroxy group. The thiazine ring is in a sofa conformation.