Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)cyclohexane-1,2-diamine-κ4O,N,N′,O′]manganese(III) perchlorate dihydrate
✍ Scribed by Akitsu, Takashiro ;Takeuchi, Yuiri ;Einaga, Yasuaki
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 292 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Diaqua[(1R,2R)-N,N 0 0 0 -bis(3,5-dibromosalicylidene)cyclohexane-1,2-diamine-j 4 O,N,N 0 0 0 ,O 0 0 0 ]manganese(III) perchlorate dihydrate
📜 SIMILAR VOLUMES
In the Mn^III^ complex of the title compound, [Mn^III^(C~18~H~12~N~4~O~2~)(H~2~O)~2~]ClO~4~, the Mn^III^ atom is coordinated by four N atoms from the bpb^2−^ [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yieldin
Diaqua-j 2 O-tris(1,10-phenanthroline)-1j 2 N,N 0 0 0 ;2j 4 N,N 0 0 0 -l-5-sulfonatoisophthalato-1:2j 4 O 1 ,O 1 0 0 0 :O 3 ,O 3 0 0 0 -dicopper(II) perchlorate trihydrate
In red crystal of the title compound, [Mn(NCS) 2 (C 6 H 8 -N 2 O 2 ) 2 (H 2 O) 2 ]Á2H 2 O, the Mn II atom lies on an inversion centre and assumes a distorted octahedral coordination geometry. Hydrogen bonds consolidate the crystal structure.