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Dianions of 3-oxodithioic acids: preparation and conversion to 3H-1,2-dithiole-3-thiones

✍ Scribed by Thomas J. Curphey; Adam H. Libby

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
129 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of ketones with CS 2 and 2 equivalents of KH in THFΒ±N,N H -dimethylpropyleneurea solution produces the dianions of 3-oxodithioic acids. These dianions are converted in good yield to 3H-1,2dithiole-3-thiones by the sequential action of hexamethyldisilathiane and an oxidizing agent such as hexachloroethane.

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