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A superior procedure for the conversion of 3-oxoesters to 3H-1,2-dithiole-3-thiones

✍ Scribed by Thomas J Curphey

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
52 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

The combination of P 4 S 10 , sulfur, and hexamethyldisiloxane converts 3-oxoesters to 3H-1,2-dithiole-3thiones in yields generally superior to those obtained with Lawesson's reagent and without the need for chromatography to remove large amounts of phosphorous-containing byproducts.

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