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Dialkoxyosmium(IV) porphyrins. Crystal and molecular structures of diethoxy-, diphenoxy-, and bis(2-propanolato)(meso-tetraphenylporphyrinato)osmium(IV)

✍ Scribed by Che, Chi Ming; Huang, Jie Sheng; Li, Zao Ying; Poon, Chung Kwong; Tong, Wai Fong; Lai, Ting Fong; Cheng, Ming Chu; Wang, Chih Chieh; Wang, Yu


Book ID
126051564
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
621 KB
Volume
31
Category
Article
ISSN
0020-1669

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Organotin(IV) compounds of 2-thiopyridin
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Dicyclohexyltin(IV) bis(2\_pyridylthiolate), compound 1, crystallizes in the orthorhombic system, a = 16&N(3), b=40.315(8) and c =7.113(3). Its molecular structure is best described as a tetrahedron, based on the two carbon-tin and the two sulfur-tin bonds, which is however strongly distorted as a c