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Dialane Anion: Three-Center Two-Electron or Two-Center One-Electron Bonded

✍ Scribed by Shan Xi Tian


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


πŸ“œ SIMILAR VOLUMES


Bishomoaromatic 1,2,4-Triboracyclopentan
✍ David Scheschkewitz; Abolfazl Ghaffari; Peter Amseis; Markus Unverzagt; Govindan πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 128 KB

The three-center, two-electron (3c,2e) bonding of bishomoaromatic cations of type 1 [1Β±4] are known to be weakened by R C 6 H 5 [2b, 3a] and displaced by R p-MeOC 6 H 4 and R OH. [4] Evidently, cations 1 are stabilized by the 3c,2e bonds, whereas cations 2 are stabilized by donor substituents R. Acc