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Two-Electron Aromatics and Homoaromatics with Three Boron Centers

✍ Scribed by C. Praesang; P. Amseis; W. Mesbah; Y. Sahin; A. Mlodzianowska; G. Geiseler; W. Massa; M. Hofmann; A. Berndt


Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The three-center, two-electron (3c,2e) bonding of bishomoaromatic cations of type 1 [1Β±4] are known to be weakened by R C 6 H 5 [2b, 3a] and displaced by R p-MeOC 6 H 4 and R OH. [4] Evidently, cations 1 are stabilized by the 3c,2e bonds, whereas cations 2 are stabilized by donor substituents R. Acc

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precursor [Cp\*Ir(PPh,)(S,fc)] (6 b) .[l91 In the very stable 18electron complexes 6 a and 6 c [S,fc] functions as a two-electron ligand. The dimeric structure of 5 has been confirmed by an X-ray crystal structure analysis for the selenium analogue, In summary, the 1,l'-ferrocenedithiolato unit [S,f