Diacetatobis[2-(2-furyl)-1H-imidazo[4,5-f][1,10]phenanthroline]cadmium(II)
✍ Scribed by Li, Chuan-Bi ;Li, Yan-Wei ;Li, De-Qian
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 243 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Cd(C 2 H 3 O 2 ) 2 (C 17 H 10 N 4 O) 2 ], the central Cd II ion (site symmetry 2) shows an uncommon eightcoordinate CdN 4 O 4 coordination geometry arising from two N,N-chelating 2-(2-furyl)-1H-imidazo[4,5-f]-1,10-phenanthroline molecules and two O,O-bidentate acetate anions. metal-organic papers Acta Cryst. (2007). E63, m286-m288 Li et al. [Cd(C 2 H 3 O 2 ) 2 (C 17 H 10 N 4 O) 2 ] m287
📜 SIMILAR VOLUMES
In the title compound, C~33~H~25~N~5~, the central benzene ring is not coplanar with any other rings. The molecules are linked through an intermolecular C—H...N hydrogen bond.
Two new chiral ruthenium(II) complexes D-[Ru(bpy) 2 (nfip)] 2+ and K-[Ru(bpy) 2 (nfip)] 2+ (in which bpy = 2,2 0 -bipyridine, nfip = 2-(5-nitrofuran-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) have been synthesized and characterized by elemental analysis, ES-MS, 1 H NMR and CD spectra. The binding
In the title linear polymeric chain compound, [Cd(C~10~H~8~O~5~)(C~12~H~8~N~2~)]~__n__~, the Cd^II^ ion exists in a monocapped triangular–prismatic geometry that is defined by two N atoms from a 1,10-phenanthroline molecule and five O atoms from three 2-(4-carboxylatophenoxy)propionate ligands. Adja