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Di-μ-hydroxo-κ4O:O-bis­[aqua­tris(triphenyl­silanolato-κO)zirconium(IV)] toluene solvate

✍ Scribed by Schweder, Bernd ;Walther, Dirk ;Imhof, Wolfgang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
234 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zr 2 (C 18 H 15 OSi) 6 (OH) 2 (H 2 O) 2 ]ÁC 7 H 8 , is a dimeric Zr IV compound. The asymmetric unit consists of two half-molecules of the complex and a toluene solvent molecule. The zirconium centres are bridged by two -hydroxo ligands. Each Zr is octahedrally coordinated by the hydroxo groups, three triphenylsilanolato groups and an additional water ligand. The centres of both Zr 2 O 2 rings are located on crystallographic centres of inversion. The two independent monomeric units differ significantly with respect to the Zr-O-Si bond angles which is most probably due to the high steric demands of three triphenylsilanolato ligands.

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