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Di-μ-fluoro-bis[bis(dimethyl sulfoxide)trifluorozirconium(IV)]

✍ Scribed by Alcock, N. W. ;Errington, W. ;Golby, S. L. ;Patterson, S. M. C. ;Wallbridge, M. G. H.


Book ID
114510562
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
206 KB
Volume
50
Category
Article
ISSN
0108-2701

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Bis(tetra­methyl­ammonium) di-μ-fluoro-b
✍ Gerasimenko, Andrey V. ;Davidovich, Ruven L. ;Tkachev, Valery V. ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

The Hf IV atoms in the centrosymmetric title compound, (C 4 H 12 N) 2 ][Hf 2 F 10 (H 2 O) 2 ], are bridged by two F atoms. The Hf IV atoms show pentagonal-bipyramidal coordination. The dianions are linked by water-fluorine hydrogen bonds into layers.