(Di-tert-butylphosphino)cobaltocenium hexafluorophosphate
✍ Scribed by Ren, Yong ;Yu, Guang-Ao ;Liu, Sheng-Hua
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 271 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 11 H 26 P 2 S 2 , displays crystallographic mirror symmetry. Key bond lengths (A Ê ) are P1ÐC(methylene) 1.8464 (18), P1ÐC(butyl) 1.8711 (13), P2ÐC(methylene) 1.8266 (18), P2ÐC(methyl) 1.7948 (15), P1 S 1.9631 (8) and P2 S 1.9552 ( 8), where P1 is the di-tert-butylphosphino P a
The structure of the title compound, C 16 H 36 N + ÁPF 6 À , has been reported previously by Angaridis, Cotton & Petrukhina [Inorg. Chim. Acta (2001), 324, 318±323]. However, these authors found the PF 6 À ion to be heavily disordered and they did not publish any coordinates. We present here a redet
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.026 A Ê R factor = 0.066 wR factor = 0.160 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê R factor = 0.048 wR factor = 0.130 Data-to-parameter ratio = 21.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.