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Di-tert-butyl 4-[2-(tert-butoxycarbonyl)ethyl]-4-nitroheptanedioate, C22H39NO8

โœ Scribed by Newkome, G. R. ;Behera, R. K. ;Baker, G. R. ;Fronczek, F. R.


Book ID
114510433
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
322 KB
Volume
50
Category
Article
ISSN
0108-2701

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(2SR,3SR,4RS)-tert-Butyl 2,3-diยญhydroxy
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The reaction of -(N-t-butoxycarbonyl)amino-,-ethylenic esters with OsO 4 yields the corresponding ,-dihydroxy compounds with good diastereoselectivity. The crystal structure of the major stereomer, (2SR,3SR,4RS)-Me 2 CHC\\forcelb]H(NHCO 2 t Bu)CHOHCHOHCO 2 t Bu, C 16 H 31 NO 6 , shows that the relat