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Di- and tri-nuclear osmium carbonyl chloride complexes: x-ray structures of Os2(CO)8Cl2and Os3(CO)12Cl2

✍ Scribed by John R. Moss; Margaret L. Niven; Elizabeth E. Sutton


Publisher
Springer
Year
1988
Tongue
English
Weight
520 KB
Volume
13
Category
Article
ISSN
0340-4285

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On the Reactivity of [(Mes)Os(CO)Cl2] To
✍ Werner, Helmut ;Stahl, Stefan ;Schulz, Michael 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 538 KB

Osmium mesitylene complexes / 0 s -R bonds, formation of / Osmium aryl hydrido compounds / Cyclohexene, generation from C6Hl1MgX I01 Reaction of [(Mes)Os(CO)Cl,] (3) with PhLi in benzene gives the diphenylosmium compound [(Mes)OsPh,(CO)] (6) whereas with PhMgBr [(Mes)OsPh(CO)Br] (7) is obtained. Tre