𝔖 Bobbio Scriptorium
✦   LIBER   ✦

DFT Study of the Role of Bridging Diphosphine Ligands in the Structure and the Internal Rotation in Quadruply Bonded Metal Dimers of the Mo 2 Cl 4 (P−P) 2 Type

✍ Scribed by Demachy, Isabelle; Lledos, Agusti; Jean, Yves


Book ID
125999492
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
67 KB
Volume
38
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis, Crystal Structure, and Bondin
✍ G. V. Khvorykh; S. I. Troyanov; A. I. Baranov; A. A. Serov 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 88 KB 👁 1 views

An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3