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Development, Synthetic Scope, and Mechanistic Studies of the Palladium-Catalyzed Cycloisomerization of Functionalized 1,6-Dienes in the Presence of Silane

โœ Scribed by Kisanga, Philip; Widenhoefer, Ross A.


Book ID
126916631
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
151 KB
Volume
122
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Cycloisomerization
โœ A. HEUMANN; M. MOUKHLISS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 24 KB ๐Ÿ‘ 2 views

Cycloisomerization of 1,6-Dienes in the Presence of Cationic Palladium Catalysts. -Mono-and dicationic palladium complexes are investigated in a preliminary study as catalysts for bis-allylic substrates. Depending on the ionic state of the catalyst, good chemoselectivities for the products are obta