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Development of the 1,2-Oxaza-Cope Rearrangement.

✍ Scribed by Armen Zakarian; Chong-Dao Lu

Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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Theoretical analysis of the Cope rearran
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✍ Shogo Sakai πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 250 KB πŸ‘ 1 views

The reaction mechanisms via the transition states of a loose chair, a loose boat, and a Dewar type for the Cope rearrangement of 1,5-hexadiene have been studied by a CiLC-IRC analysis on the basis of a complete active space self-consistent field (CASSCF) molecular orbital (MO) method. The CiLC-IRC a