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Development of new asymmetric two-center catalysts in phase-transfer reactions

โœ Scribed by Tomoyuki Shibuguchi; Yuhei Fukuta; Yoko Akachi; Akihiro Sekine; Takashi Ohshima; Masakatsu Shibasaki


Book ID
104252537
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
106 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


A new asymmetric two-center phase-transfer catalyst was designed and a catalyst library containing more than 40 new two-center catalysts was constructed. The catalysts were applied in phase-transfer alkylations and Michael additions to afford the corresponding products in up to 93% ee and 82% ee, respectively.


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