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Catalytic asymmetric phase-transfer reactions using tartrate-derived asymmetric two-center organocatalysts

โœ Scribed by Takashi Ohshima; Tomoyuki Shibuguchi; Yuhei Fukuta; Masakatsu Shibasaki


Book ID
108282638
Publisher
Elsevier Science
Year
2004
Tongue
French
Weight
446 KB
Volume
60
Category
Article
ISSN
0040-4020

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Development of new asymmetric two-center
โœ Tomoyuki Shibuguchi; Yuhei Fukuta; Yoko Akachi; Akihiro Sekine; Takashi Ohshima; ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 106 KB

A new asymmetric two-center phase-transfer catalyst was designed and a catalyst library containing more than 40 new two-center catalysts was constructed. The catalysts were applied in phase-transfer alkylations and Michael additions to afford the corresponding products in up to 93% ee and 82% ee, re