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Development of Isomerization and Cycloisomerization with Use of a Ruthenium Hydride with N-Heterocyclic Carbene and Its Application to the Synthesis of Heterocycles.

✍ Scribed by Mitsuhiro Arisawa; Yukiyoshi Terada; Kazuyuki Takahashi; Masako Nakagawa; Atsushi Nishida


Publisher
John Wiley and Sons
Year
2006
Weight
46 KB
Volume
37
Category
Article
ISSN
0931-7597

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The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes ) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.