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Selenoimidoylation of Alcohols with Selenium and Isocyanides and Its Application to the Synthesis of Selenium-Containing Heterocycles.

โœ Scribed by Yoshiaki Asanuma; Shin-ichi Fujiwara; Tsutomu Shin-ike; Nobuaki Kambe


Publisher
John Wiley and Sons
Year
2004
Weight
31 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœ Xiaoyuan Chen; Weihui Zhong; Yongmin Zhang ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 207 KB

## Abstract Treatment of bis(oโ€nitrophenyl)diselenides with SmI~2~ led to simultaneous reduction of nitro groups and reductive cleavage of Se๏ฃฟSe bonds as well as to the formation of the intermediates **2**. The intermediates **2** were โ€œlivingโ€ doubleโ€anions formed in situ, and reacted readily with