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Development of 4,4′-Substituted-XylBINAP Ligands for Highly Enantioselective Hydrogenation of Ketones.

✍ Scribed by Helen L. Ngo; Wenbin Lin

Publisher
John Wiley and Sons
Year
2005
Weight
34 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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A family of stereodefined, modular amino alcohols (3-alkoxy-1-amino-1-phenyl-2-propanols), in which the steric bulk of the alkoxy and amino substituents varies smoothly, has been synthesized from enantiomerically pure phenylglycidol, prepared by Sharpless epoxidation. These amino alcohols have been