Development and in situ synthesis of monolithic stationary phases for electrochromatographic separations
✍ Scribed by Nathalie Delaunay-Bertoncini; Claire Demesmay; Jean-Louis Rocca
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 241 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0173-0835
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## Abstract Propargyl acrylate‐based functionalizable monolithic stationary phase (FMSP) for capillary electrochromatography, easily modifiable by alkyne–azide 1,3‐dipolar cycloaddition, is developed. Optimization of FMSP is focused on (i) physical properties: rigidity, stability, and pore size and
## Abstract A porous zwitterionic monolith was prepared by __in situ__ covalent attachment of lysine to a γ‐glycidoxypropyltrimethosysilane‐modified silica monolith. The prepared column was used to perform neutral and ionized solutes separations by pressurized (pCEC). Due to the zwitterionic nature