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Development and Application of a Direct Vinyl Lithiation of cis-Stilbene and a Directed Vinyl Lithiation of an Unsymmetrical cis-Stilbene.

โœ Scribed by Juliet Cotter; Anne-Marie L. Hogan; Donal F. O'Shea


Publisher
John Wiley and Sons
Year
2007
Weight
30 KB
Volume
38
Category
Article
ISSN
0931-7597

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A Concise Total Synthesis of (ยฑ)-cis-and (ยฑ)-trans-Clavicipitic Acids by Combinatorial Use of Directed Lithiation and Fluoride Ion-Induced Elimination-Addition Reaction of 1-(Triisopropylsilyl)gramine Derivatives. -The key steps in the synthesis of the title compounds (VIII) and (IX) are regioselec