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Deuterium Substitution Effect on the Excited-State Dynamics of Rhodopsin †

✍ Scribed by Kakitani, T.; Akiyama, R.; Hatano, Y.; Imamoto, Y.; Shichida, Y.; Verdegem, P.; Lugtenburg, J.


Book ID
125893274
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
135 KB
Volume
102
Category
Article
ISSN
0022-3654

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The central C atom of the OCCCO skeleton of the malonaldehyde molecule is replaced by N, and the effects upon the intramolecular H-bond and the proton transfer are monitored by ab initio calculations in the ground and excited electronic states. The H-bond is weakened in the singlet and triplet state