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Deuterium solvent isotope effects on reactions involving the aqueous hydroxide ion

โœ Scribed by Gold, V.; Grist, S.


Book ID
120610538
Publisher
Royal Society of Chemistry
Year
1972
Tongue
English
Weight
937 KB
Volume
1
Category
Article
ISSN
1472-779X

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Solvent effects on reactions of hydroxid
โœ Clifford A. Bunton; Nicholas D. Gillitt; Anurag Kumar ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 544 KB

## Second-order rate constants of reactions of HO-with phosphate, phosphinate and thiophosphinate esters, (PhO)2P0.0C6H4NO~~p, Ph,PO.OC,H,NO,-p, Ph,PO.SPh, Ph,PO.SC,H,NO,-p and Ph,PO.SEt, go through minima with decreasing water content of H,O-MeCN or H,O-t-BuOH. The rate decrease is due to stabili