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Deuterium Oxide Solvent Isotope Effects in the Nucleophilic Reactions of Phenyl Esters

✍ Scribed by Bender, Myron L.; Pollock, Edward J.; Neveu, Maurice C.

Book ID
126438869
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
626 KB
Volume
84
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Solvent deuterium isotope effect on the
Solvent deuterium isotope effect on the oxidation of o-diphenols by tyrosinase
✍ Marı́a JosΓ© PeΓ±alver; JosΓ© Neptuno Rodrı́guez-LΓ³pez; P.A. Garcı́a-Ruiz; Francisc πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 648 KB

A solvent deuterium isotope effect on the catalytic affinity (K(m)) and rate constant (k(cat)) of tyrosinase in its action on 4-tert-butylcatechol (TBC) was observed. Both parameters decreased as the molar fraction of deuterated water in the medium increased, while the k(cat)/K(m) ratio remained con