Deuterium NMR in the solid-state and in solution of the molecular motion of the bases in poly(I) and poly(I)·poly(C)
✍ Scribed by BENDEL, P; MURPHYBOESCH, J; JAMES, T
- Book ID
- 125461000
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 696 KB
- Volume
- 759
- Category
- Article
- ISSN
- 0304-4165
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📜 SIMILAR VOLUMES
The fixation of trans-(NH&Clz Pt(I1) to poly(1)-poly(C) a t low rb (<0.05) leads to the formation of two complexed species. The major species (ca. 82% of bound platinum) involves coordination of platinum to a single hypoxanthine base, while the other species involves coordination of two hypoxanthine
The fixation of cis(NH&C12Pt(II) to poly(1)-poly(C) leads to the formation of two complexed species. One involves coordination to a single base (accounting for about 70% of the total platinum bound over the Fb range 0.07-0.25) and the other to two bases which are not adjacent to each other but may b