Deuterium isotope effects on noncovalent interactions between molecules
✍ Scribed by David Wade
- Book ID
- 114009665
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 154 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0009-2797
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## Abstract Deuterium isotope effects on ^13^C NMR chemical shifts, (^2^H/^1^H)^__n__^Δ(^13^C), of 2‐methylene‐__d__~2~‐adamantane, 4‐methylene‐__d__~2~‐2‐adamantanone and 6‐methylene‐__d__~2~‐2‐adamantanone are presented. Long‐range effects (^4^Δ, ^5^Δ and ^6^Δ) in a range from 5 to – 23 ppb were
In a recent cosnxurlcation (1) we concluded that reasonable estimates of secotiary deuterium isotope effects caused by rronbotied interactions may be obtained by using Bartell's procedure (2). Particularly disturbing was the discrepancy between the experlmentat isotope effect,