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Deuterium Isotope Effects in the Photochemistry of 2-Hexanone

✍ Scribed by Coulson, D. Robert; Yang, N. C.

Book ID: 127270047
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 363 KB
Volume: 88
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00971a041

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## Abstract Proton and deuterium n.m.r. measurements in acetylacetone and 3,3‐d~2~‐acetylacetone are reported. Deuterium‐isotope effects on chemical shifts and keto–enol equilibria as a function of concentration in the two solvents triethylamine and pyrrole are determined. A strong solvent concentr