Deuterium Isotope Effect on the Atomic Orbital Alignment Dependence in the Reaction of the Oriented Ar ( 3 P 2 ) with CH 3 CN (CD 3 CN)
โ Scribed by Matsumura, Takashi; Ohoyama, Hiroshi; Watanabe, Daisuke; Yasuda, Keisuke; Kasai, Toshio
- Book ID
- 127048764
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 270 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
FTIR spectra of the four isotopically substituted 1:1 complexes of acetonitrile and boron trifluoride were recorded in Ar, N 2 and Xe matrices. In Ar, previously unreported three vibrational modes of the complex were clearly observed. Several significant vibrational bands were also observed in N 2 a
The violet emission spectrum (B\* Z-X' C) of the CN radical observed by the collision of HCN with metastable AI(~P, ?) atoms was analyzed. The effective rotational temperature of the CN(B2C) radical, 3s estimated from a band e&elope analysis, is about 2000ยฐK. The disrributions of the excess energy t