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Deuteration of proteins and polyamides in deuterium oxide vapor

✍ Scribed by Jeffries, R.


Publisher
Wiley (John Wiley & Sons)
Year
1964
Tongue
English
Weight
555 KB
Volume
2
Category
Article
ISSN
0449-2951

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πŸ“œ SIMILAR VOLUMES


Specific deuteration of phenols and arom
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A number of phenols and aromatic ethers were dcuterated in positions ortho and para to the phenolic groups using BF, etherate followed by quenching with Na,CO, in D,O. This method involves mild reaction conditions and should have wide applicability in the isotopic labeling of these compounds.

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## Abstract Aromatic compounds bearing an __ortho__‐directing substituent may be deuterated by exchange with deuterium oxide in the presence of a range of cycloocta‐1,5‐dienyliridium(I)1,3‐dionate catalysts. The exchange takes place in several dipolar aprotic solvents and is directly applicable to