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Specific deuteration of phenols and aromatic ethers using boron trifluoride and deuterium oxide

✍ Scribed by Ali R. Banijamali; Avgui Charalambous; Cornelis J. van der Schyf; Alexandros Makriyannis

Publisher
John Wiley and Sons
Year
1987
Tongue
French
Weight
155 KB
Volume
24
Category
Article
ISSN
0022-2135

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✦ Synopsis

A number of phenols and aromatic ethers were dcuterated in positions ortho and para to the phenolic groups using BF, etherate followed by quenching with Na,CO, in D,O. This method involves mild reaction conditions and should have wide applicability in the isotopic labeling of these compounds.

πŸ“œ SIMILAR VOLUMES

Stereoselective glycosylation of Alcohol
Stereoselective glycosylation of Alcohols and Silyl Ethers Using Glycosyl Fluorides and Boron Trifluoride Etherate
✍ Horst Kunz; Wilfried Sager πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 German βš– 301 KB

## Abstract The stereoselective glycosylation of alcohols and their silyl ethers has been achieved using __O__‐alkyl‐, __O__‐acyl‐, and acetal‐protected glycosyl fluorides of the pyranose and furanose series and boron trifluoride etherate in CH~2~Cl~2~.

Regioselective deuteration of aromatic a
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Ortho-deuterated aromatic carboxylic acids and p-deuterated a,p -unsaturated carboxylic acids may be prepared with high regioselectivity by exchange deuteration of the unlabelled acids in the presence of rhodium(II1) chloride.