✦ LIBER ✦

Deuterated methyl cation reactions with atomic oxygen

✍ Scribed by A.A. Viggiano; R.A. Morris; J.F. Paulson; E.E. Ferguson

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 244 KB
Volume: 148
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87275-0

No coin nor oath required. For personal study only.

✦ Synopsis

The rate constants for the reactions between CD,Hf_, and 0 have been measured and found to be fast, independent of isotope. The branching ratio for these reactions has been found to be statistical. Since decay of metastable triplet CD*HO+ shows a large isotope effect, it was thought that the present reactions might also do so. The fact that the present experiments do not show this large isotope effect is ascribed to the large exothermicity of reaction CH: +O-tHCO++H,, which opens several alternative pathways not involving metastable triplet CD2HO+ as the intermediate.

📜 SIMILAR VOLUMES

Reaction of methyl radicals with atomic

Reaction of methyl radicals with atomic oxygen

✍ E. D. Morris Jr.; H. Niki 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

## Abstract The reaction of hydrogen atoms with diazomethane was used as a source of methyl radicals to study the reaction of oxygen atoms with methyl radicals. This investigation verifies directly the earlier results that formaldehyde is a major product and that the rate constant is greater than 3

The reactions of methyl radicals with at

The reactions of methyl radicals with atomic and molecular oxygen

✍ N. Washida; Kyle D. Bayes 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 925 KB

## Abstract The reaction of methyl radicals with atomic and molecular oxygen was studied with a photoionization mass spectrometer. The methyl radicals were generated by reacting oxygen atoms with ethylene in a fast‐flow tube reactor. The rate constant for the reaction of methyl radicals with oxygen

The rate of reaction of methyl radicals

The rate of reaction of methyl radicals with atomic oxygen

✍ N. Washida; Kyle D. Bayes 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 249 KB

Reaction of atomic oxygen with cyclopent

Reaction of atomic oxygen with cyclopentadiene

✍ Kazumoto Nakamura; Seiichiro Koda 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 662 KB

The reaction of 1,3-cyclopentadiene (CPD) with ground-state atomic oxygen O ( 3 P ) , produced by mercury photosensitized decomposition of nitrous oxide, was studied. The identified products were carbon monoxide and the following C4H6 isomers: 3-methylcyclopropene, 1,3-butadiene, 1,2-butadiene, and

Reaction of H and D atoms with deuterate

Reaction of H and D atoms with deuterated propylenes

✍ W. E. Falconer; W. A. Sunder 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 1 views

## Abstract Effects of deuterium substitution in propylene on the relative rates of H(D) atom abstraction from and addition to the olefin, and on the orientation of H(D) atom addition, have been studied in the gas phase at room temperature. Effects of isotopic substitution of the olefinic hydrogen

Unimolecular gas-phase reactions of the

Unimolecular gas-phase reactions of the methyl acetoacetate radical cation. Oxygen atom permutation via ion-molecule complexes

✍ Dorothée Berthomieu; Jeanine Tortajada; Jean-Pierre Morizur; Henri-Edouard Audie 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 588 KB

The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO