✦ LIBER ✦

Determination of triplet quantum yields by laser flash absorption spectroscopy

✍ Scribed by B. Amand; R. Bensasson

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 432 KB
Volume: 34
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)80197-7

No coin nor oath required. For personal study only.

✦ Synopsis

A general method based an a relative actinometry using the laser flash spectroscopy technique has been developed for the determination of the quantum yield of trip!et state formation $T. &l-values for 17 aromatic compounds in cyclohexane or benzene at room temperature have been obtained in good agreement with previous meaarements.

Triplet-triplet extinction coefficients necessary for the 0~ calculations and determined via enerm transfer are also reported. Conditions of application and limitations or this method are outlined.

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