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Determination of the Velocity Coefficients for Polymerization Processes. II. The Photosensitized Polymerization of Vinyl Acetate by Benzoyl Peroxide

✍ Scribed by Burnett, G. M.; Melville, H. W.


Book ID
120146489
Publisher
The Royal Society
Year
1947
Tongue
English
Weight
517 KB
Volume
189
Category
Article
ISSN
0962-8444

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Kinetics of Bz202-initiated polymerization of VAC in pyridine at 60 Β° were investigated. The polymerization was significantly retarded by pyridine. The monomer exponent decreased from 2.5 at a relatively low [Bz2Oz] (1.0 x 10 -2 M) to 2.0 at [Bz202] /> 4.0 x 10 -2 M. The observed kinetic features we