✦ LIBER ✦

Studies on the kinetics of polymerization of vinyl acetate by benzoyl peroxide at 60° using pyridine as solvent

✍ Scribed by P. Ghosh; G. Mukhopadhyay

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 293 KB
Volume: 15
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(79)90199-x

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✦ Synopsis

Kinetics of Bz202-initiated polymerization of VAC in pyridine at 60 ° were investigated. The polymerization was significantly retarded by pyridine. The monomer exponent decreased from 2.5 at a relatively low [Bz2Oz] (1.0 x 10 -2 M) to 2.0 at [Bz202] /> 4.0 x 10 -2 M. The observed kinetic features were explained on the basis of degradative chain transfer and copolymerization with pyridine.

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