For some lower-lying excited states of NH3 and H20, ab initio SCF calculations indicate the presence of potential maxima in the paths leading to dissociation into NH2 +H and OH +H. The occurrence of these maxima is probably connected with changes in the highest occupied molecular orbital during diss
Determination of the translational energy of O(3s3S) excited in the dissociative excitation of O2, and NO by He*(23S)
โ Scribed by Lawrence G. Piper; Michael A.A. Clyne
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 550 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The
ScvcraI mcaurcments have been made by various authors on the relative contnbutmn to the Halmcra crntrsiun or the 35 state of hydrogen atolns rcsultlng frown the dlrsociatwe evcltation of El2 by electrons in the energy range 20 to 500 cV. Thcsc mcasurcmcnts, however, arc mutually Inconsistent c\cept