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Determination of the thermodynamic properties of solid solutions of CoO and MgO by a solid-electrolyte galvanic cell in the temperature range 1273 to 1473 K

โœ Scribed by M Rigaud; G Giovannetti; M Hone


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
336 KB
Volume
6
Category
Article
ISSN
0021-9614

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The activities of CaO and CoO in {xCaO + (1x)CoO} have been determined in the temperature range T = 1173 K to T = 1373 K by solid-electrolyte galvanic cells. The solubility limits of CaO in CoO and CoO in CaO have been estimated. The solutions deviate strongly from ideal behaviour.

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The activities of CuO and NiO in {xCuO + (1x)NiO} have been determined in the temperature range 1170 K to 1370 K by solid-electrolyte galvanic cells. The solubility limits of CuO in NiO and NiO in CuO have been estimated. The solutions exhibit strong positive deviations from ideal behaviour.

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The {xMnO + (1x)NiO} solid solutions were studied thermodynamically in the temperature range from 973 K to 1173 K by solid-state galvanic cells containing b0-alumina electrolytes conducting manganese(II) and nickel(II) ions, respectively. The experimental procedure allowed us to determine the NiO an