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Determination of the activities in {xMnO+(1−x)NiO} by solid-electrolyte galvanic cells in the temperature range 973 K to 1173 K

✍ Scribed by G. Róg; A. Kozlowska-Róg

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
204 KB
Volume
29
Category
Article
ISSN
0021-9614

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✦ Synopsis

The {xMnO + (1x)NiO} solid solutions were studied thermodynamically in the temperature range from 973 K to 1173 K by solid-state galvanic cells containing b0-alumina electrolytes conducting manganese(II) and nickel(II) ions, respectively. The experimental procedure allowed us to determine the NiO and MnO activities directly from the e.m.f. measurements. The solutions exhibited positive deviation from ideal behaviour, but they could be regarded as regular solutions.

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