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Determination of the Stereochemistry of Four Spirodiastereoisomers by One- and Two-Dimensional NOE Studies

✍ Scribed by A. Moreno; A. Díaz-Ortiz; E. Díez-Barra; A. de la Hoz; F. Langa; P. Prieto; T. D. W. Claridge

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
414 KB
Volume
34
Category
Article
ISSN
0749-1581

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✦ Synopsis

The stereochemistries of four cycloadducts obtained by 1,3-dipolar reactions were investigated with one-and twodimensional NMR techniques. Analysis of a series of homonuclear NOE difference spectra and COSY and NOESY spectra recorded in a variety of solvents and at various temperatures allowed the determination of the full stereochemistry of each adduct.

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