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Determination of the Reaction Rate Constants and Decomposition Mechanisms of Ozone with Two Model Emerging Contaminants: DEET and Nortriptyline

✍ Scribed by Benitez, F. Javier; Acero, Juan L.; Garcia-Reyes, Juan F.; Real, Francisco J.; Roldan, Gloria; Rodriguez, Elena; Molina-Díaz, Antonio

Book ID
121390649
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
503 KB
Volume
52
Category
Article
ISSN
0888-5885

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Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 Ϯ 2 K 740 Ϯ 5 torr pressure are: Ϫ11 3 Ϫ1 Ϫ1 Ϫ18 3 k ϭ (3.9 Ϯ 1.