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Determination of the rate constants for a CECE reduction mechanism

✍ Scribed by A.M. Heras; E. Muñoz; J.L. Avila; L. Camacho

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
244 KB
Volume
32
Category
Article
ISSN
0013-4686

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✦ Synopsis

We have made a generalized treatment of first-order kinetic processes in dc polarography, obtaining approximate analytic expressions, applicable to any conditions. This treatment is applied to the electrochemical reduction of 0-nitrophenol, which undergoes a CECE mechanism in which both chemical stages influence the process simultaneously. All the rate constants involved in the process have been calculated.

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