𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Determination of the order of a reaction and calculation of the initial rate by absorption spectroscopy

✍ Scribed by H. N. Koning; K. G. van Senden

Book ID
104586554
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
231 KB
Volume
81
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The determination of the order of a chemical reaction using linear functions obtained from absorption spectroscopic data is described. The calculation of the initial rate by this method is given.

πŸ“œ SIMILAR VOLUMES

Determination of the absolute third-orde
Determination of the absolute third-order rate constant for reaction between Cs + O2 + N2 by time-resolved atomic resonance absorption spectroscopy
✍ David Husain; Bing Ji πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 971 KB

The absolute third-order rate constant for the recombination between Cs + O2 + Nz was studied by time-resolved atomic resonance absorption spectroscopy following pulsed irradiation of CsCl vapour at elevated temperatures. CS(~~S,,~), generated on photolysis, was monitored photoelectrically in absorp

A differential technique which is indepe
A differential technique which is independent of initial conditions for calculating the rate constant of a second-order reaction
✍ Walter Y. Wen πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 340 KB πŸ‘ 1 views

## Abstract It has been shown that experimental errors of the initial conditions of a second‐order reaction can cause erroneous results with the rate constant calculated directly from the differential or integrated rate expression. By means of a computer method, a differential technique has been de

Differential method for the determinatio
Differential method for the determination of the order of reaction and the rate constants
✍ S. D. Ross πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 282 KB πŸ‘ 1 views

## Abstract A method is proposed whereby the orders and rate constants for processes obeying the rate law βˆ’__dA__/__dt__ = __kA__^n^ may be determined. The method is illustrated in two ways. First, simulated data for processes of various orders are treated, and the treatment is shown to be capable