✦ LIBER ✦
A differential technique which is independent of initial conditions for calculating the rate constant of a second-order reaction
✍ Scribed by Walter Y. Wen
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 340 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Abstract
It has been shown that experimental errors of the initial conditions of a second‐order reaction can cause erroneous results with the rate constant calculated directly from the differential or integrated rate expression. By means of a computer method, a differential technique has been developed so that precise initial reactant conditions are not necessary for calculating a second‐order rate constant if continuous measurements of a single reaction variable are available. The technique has been successfully applied to the data of Kistiakowsky and Lacher on the condensation of acrolein and butadiene.